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Silicon microprotrusions with tailored chirality enabled by direct femtosecond laser ablation
(2020)
Here, we report on formation of nanoprotrusions on the surface of a bulk crystalline silicon wafer under femtosecond-laser ablation with a donut-shaped laser beam. By breaking circular symmetry of the irradiating donut-shaped fs-pulse beam, a switch in geometry of the formed surface nanoprotrusions from regular to chiral was demonstrated. The chirality of the obtained Si nanostructures was promoted with an asymmetry degree of the laser beam. An uneven helical flow of laser-melted Si caused by asymmetry of the initial intensity and temperature pattern on the laser-irradiated Si surface explains this phenomenon. Chirality of the formed protrusions was confirmed by visualizing cross-sectional cuts produced by focused ion beam milling as well as Raman activity of these structures probed by circularly polarized light with opposite handedness. Our results open a pathway towards easy-to-implement inexpensive …
Redistribution of deep selenium and sulfur impurities in silicon upon surface doping with phosphorus
(2009)
The study is concerned with the effect of short-term high-temperature heating on Si:Se and Si:S samples, whose surface layers are doped with phosphorus to high concentrations. It is found that the resistivity of the wafers substantially increases deep in the bulk within up to similar to 10 mu m. The experimental data suggest that this effect is due to enhanced diffusion of chalcogen in the presence of the phosphorus-doped surface region. The mechanism of the effect is the injection of nonequilibrium interstitial silicon atoms from the layer heavily doped with phosphorus to the bulk of the sample. This results in a shift of the equilibrium between the concentrations of substitutional and interstitial impurity atoms towards higher concentrations of interstitials and, as a consequence, towards the increase in the relative content of the fast-diffusing interstitial component of the impurity.
The production of free-standing large aspect ratio metal nanofilms by femtosecond laser separation
(2009)
We demonstrate a new method for the production of free-standing metal films of thickness down to several tens of nanometres. Films of different metals as well as multilayer structures have been produced by means of femtosecond laser-induced separation of evaporated layers from a plane glass surface. This technology enables the production of large-area films with different properties for optical or nanotechnological applications. We study the properties of the film and demonstrate the possibility of high-pass filtering of electrons with an energy of several keV by means of the free-standing films. The physical mechanisms leading to the film separation under femtosecond laser radiation are discussed.
A new simple design of a high-efficiency low-transport-time cell for laser ablation is presented. The main feature of the design is that the particles are transported by a laminar spiral gas flow into the outlet without any contact with the cell walls. The efficiency of the particle transport and the dependence of the ICP-MS peak shape on experimental conditions were measured. The peak duration on the 10% level was found to be as short as 30 ms and the transport efficiency reached 100% when analysing a standard brass sample. As an example of application to real samples with fine inhomogeneities, the profiles of C-13, Ca-44 and Pb-208 were measured by LA-ICP-MS across a tree core. As a result, the very quick particle transport time of the cell enabled the fine, seasonal variation in wood composition to be resolved.
The mechanisms of femtosecond laser-induced transient melting and atomic mixing in a target composed of a 30 nm Au film deposited on a bulk Cu substrate are investigated in a series of atomistic simulations. The relative strength and the electron temperature dependence of the electron-phonon coupling of the metals composing the layered target are identified as major factors affecting the initial energy redistribution and the location of the region(s) undergoing transient melting and resolidification. The higher strength of the electron-phonon coupling in Cu, as compared to Au, results in a preferential sub-surface heating and melting of the Cu substrate, while the overlaying Au film largely retains its original crystalline structure. The large difference in the atomic mobility in the transiently melted and crystalline regions of the target makes it possible to connect the final distributions of the components in the resolidified targets to the history of the laser-induced melting process, thus allowing for experimental verification of the computational predictions. (C) 2009 Elsevier B. V. All rights reserved.
In this paper a novel concept of ablation cell for laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is presented. Suppression of the turbulence in the flush gas flow in the ablation region reduces the wash-out time of the ablation cell considerably. An ablation chamber which enables ICP-MS pulse duration down to several ten milliseconds has been designed. Dependence of the ICP-MS peak amplitude, width, and shape on the gas flow parameters is studied experimentally for aerosol ablated under laminar and turbulent conditions. Experiments demonstrate that the ICP-MS peak becomes sharper and the amplitude of the signal grows as the turbulence in the ablation cell is suppressed. Furthermore, the possibility of the LA-ICP-MS analysis with a sampling rate of more than 10 Hz has been demonstrated. Express in-depth profiling in the new ablation cell is demonstrated on examples of an Al -Zn multilayer structure and an industrial Mg -Zn coating.
The dewetting of liquid filaments in linear grooves of a triangular cross section is studied experimentally and theoretically. Homogeneous filaments of glassy polystyrene (PS) are prepared in triangular grooves in a nonequilibrium state. At elevated temperatures, the molten PS restores its material contact angle with the substrate. Liquid filaments with a convex liquid-vapor interface decay into isolated droplets with a characteristic spacing depending on the wedge geometry, wettability, and filament width. This instability is driven by the interplay of local filament width and Laplace pressure and constitutes a wide class of ID instabilities that also include the Rayleigh -Plateau instability as a special case. Our results show an accurately exponential buildup of the instability, suggesting that fluctuations have a minor influence in our system.
