TY - JOUR A1 - Gurevich, E. L. A1 - Hergenröder, R. T1 - Femtosecond laser-induced breakdown spectroscopy: Physics, applications, and perspectives JF - Appl. Spectroscopy Y1 - 2007 SN - 0003-7028 VL - 61 SP - 233A EP - 242A ER - TY - JOUR A1 - Khare, K. A1 - Brinkmann, M. A1 - Law, B. M. A1 - Gurevich, E. L. A1 - Herminghaus, S. A1 - Seemann, R. T1 - Dewetting of liquid filaments in wedge-shaped grooves JF - Langmuir N2 - The dewetting of liquid filaments in linear grooves of a triangular cross section is studied experimentally and theoretically. Homogeneous filaments of glassy polystyrene (PS) are prepared in triangular grooves in a nonequilibrium state. At elevated temperatures, the molten PS restores its material contact angle with the substrate. Liquid filaments with a convex liquid-vapor interface decay into isolated droplets with a characteristic spacing depending on the wedge geometry, wettability, and filament width. This instability is driven by the interplay of local filament width and Laplace pressure and constitutes a wide class of ID instabilities that also include the Rayleigh -Plateau instability as a special case. Our results show an accurately exponential buildup of the instability, suggesting that fluctuations have a minor influence in our system. Y1 - 2007 U6 - http://dx.doi.org/10.1021/la701515u SN - 0743-7463 VL - 23 SP - 12138 EP - 12141 ER - TY - JOUR A1 - Gurevich, E. L. A1 - Hergenröder, R. T1 - A simple laser ICP-MS ablation cell with wash-out time less than 100 ms JF - J. An. At. Spectr. N2 - In this paper a novel concept of ablation cell for laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is presented. Suppression of the turbulence in the flush gas flow in the ablation region reduces the wash-out time of the ablation cell considerably. An ablation chamber which enables ICP-MS pulse duration down to several ten milliseconds has been designed. Dependence of the ICP-MS peak amplitude, width, and shape on the gas flow parameters is studied experimentally for aerosol ablated under laminar and turbulent conditions. Experiments demonstrate that the ICP-MS peak becomes sharper and the amplitude of the signal grows as the turbulence in the ablation cell is suppressed. Furthermore, the possibility of the LA-ICP-MS analysis with a sampling rate of more than 10 Hz has been demonstrated. Express in-depth profiling in the new ablation cell is demonstrated on examples of an Al -Zn multilayer structure and an industrial Mg -Zn coating. Y1 - 2007 U6 - http://dx.doi.org/10.1039/b704700b SN - 0267-9477 VL - 22 SP - 1043 EP - 1050 ER -