@article{KaoukRuokoGonulluetal.2015, author = {Kaouk, A. and Ruoko, T.-P. and Gonullu, Y. and Kaunisto, K. and Mettenborger, A. and Gurevich, E. and Lemmetyinen, H. and Ostendorf, A. and Mathur, S.}, title = {Graphene-intercalated Fe₂O₃/TiO₂ heterojunctions for efficient photoelectrolysis of water}, series = {RSC Adv}, volume = {5}, journal = {RSC Adv}, doi = {10.1039/C5RA18330H}, pages = {101401 -- 101407}, year = {2015}, abstract = {Interfacial modification of [small alpha]-Fe2O3/TiO2 multilayer photoanodes by intercalating few-layer graphene (FLG) was found to improve water splitting efficiency due to superior transport properties, when compared to individual iron and titanium oxides and heterojunctions thereof. Both metal oxides and graphene sheets were grown by plasma-enhanced chemical vapor deposition. Compared to the onset potential achieved for [small alpha]-Fe2O3 films (1 V vs. RHE), the [small alpha]-Fe2O3/TiO2 bilayer structure yielded a better onset potential (0.3 V vs. RHE). Heterojunctioned bilayers exhibited a higher photocurrent density (0.32 mA cm-2 at 1.23 V vs. RHE) than the single [small alpha]-Fe2O3 layer (0.22 mA cm-2 at 1.23 V vs. RHE), indicating more efficient light harvesting and higher concentration of photogenerated charge carriers. For more efficient charge transport at the interface, a few layer graphene sheet was intercalated into the [small alpha]-Fe2O3/TiO2 interface, which substantially increased the photocurrent density to 0.85 mA cm-2 (1.23 V vs. RHE) and shifted the onset potential (0.25 V vs. RHE). Ultrafast transient absorption spectroscopy studies indicated that the incorporation of FLG between the [small alpha]-Fe2O3 and TiO2 layers resulted in reduced recombination in the [small alpha]-Fe2O3 layer. The results showed that graphene intercalation improved the charge separation and the photocurrent density of the FTO/[small alpha]-Fe2O3/FLG/TiO2 system.}, language = {en} } @article{ChakifEssaidiGurevichetal.2014, author = {Chakif, M. and Essaidi, A. and Gurevich, E. and Ostendorf, A. and Prymak, O. and Epple, M.}, title = {Gene­ration of NiTi Nanoparticles by Femtosecond Laser Ablation in Liquid}, series = {J Mat. Eng. Perf.}, volume = {23}, journal = {J Mat. Eng. Perf.}, issn = {1059-9495}, doi = {10.1007/s11665-014-1007-7}, pages = {2482 -- 2486}, year = {2014}, language = {en} }