@article{DittelCicekBredoletal.2023, author = {Dittel, G{\"o}zdem and {\c{C}}i{\c{c}}ek, Irem Ecem and Bredol, Michael and Gries, Thomas}, title = {Carbon Rovings as Strain Sensor in TRC Structures: Effect of Roving Cross-Sectional Shape and Coating Material on the Electrical Response under Bending Stress}, series = {Sensors}, volume = {23}, journal = {Sensors}, doi = {10.3390/s23104601}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:836-opus-170823}, pages = {4601}, year = {2023}, abstract = {This study investigated the ability of electrically conductive carbon rovings to detect cracks in textile-reinforced concrete (TRC) structures. The key innovation lies in the integration of carbon rovings into the reinforcing textile, which not only contributes to the mechanical properties of the concrete structure but also eliminates the need for an additional sensory system, such as strain gauges, to monitor the structural health. Carbon rovings are integrated into a grid-like textile reinforcement that differs in binding type and dispersion concentration of the styrene butadiene rubber (SBR) coating. Ninety final samples were subjected to a four-point bending test in which the electrical changes of the carbon rovings were measured simultaneously to capture the strain. The mechanical results show that the SBR50-coated TRC samples with circular and elliptical cross-sectional shape achieved, with 1.55 kN, the highest bending tensile strength, which is also captured with a value of 0.65 Ω by the electrical impedance monitoring. The elongation and fracture of the rovings have a significant effect on the impedance mainly due to electrical resistance change. A correlation was found between the impedance change, binding type and coating. This suggests that the elongation and fracture mechanisms are affected by the number of outer and inner filaments, as well as the coating.}, language = {en} } @article{DingaBredolKynast2023, author = {Dinga, Daniel and Bredol, Michael and Kynast, Ulrich}, title = {Design and Mechanism of Rare-Earth Singlet Oxygen Sensing: An Experimental and Quantum Chemical Approach}, series = {Journal of Physical Chemistry A}, volume = {127}, journal = {Journal of Physical Chemistry A}, number = {5}, issn = {1089-5639}, doi = {10.1021/acs.jpca.2c06339}, pages = {1130 -- 1140}, year = {2023}, language = {en} } @incollection{VoigtBredol2022, author = {Voigt, Dominik and Bredol, Michael}, title = {Semiconductors}, series = {Applied Inorganic Chemistry, Hrsg. Rainer P{\"o}ttgen, Cristian Strassert, Thomas J{\"u}stel, Vol.3}, booktitle = {Applied Inorganic Chemistry, Hrsg. Rainer P{\"o}ttgen, Cristian Strassert, Thomas J{\"u}stel, Vol.3}, editor = {P{\"o}ttgen, Rainer and Strassert, Cristian and J{\"u}stel, Thomas}, publisher = {De Gruyter}, address = {Berlin}, isbn = {978-3-11-073837-7}, doi = {10.1515/9783110733471-001}, publisher = {FH M{\"u}nster - University of Applied Sciences}, pages = {1 -- 22}, year = {2022}, language = {en} } @article{BredolVoigtPrimaveraetal.2022, author = {Bredol, Michael and Voigt, Dominik and Primavera, Giulia and Uphoff, Holger and Rethmeier, Jan and Schepp, Lukas}, title = {Ternary Chacogenide-Based Quantum Dots and Carbon Nanotubes: Establishing a Toolbox for Controlled Formation od Nanocomposites}, series = {The Journal of Physical Chemistry C}, volume = {126}, journal = {The Journal of Physical Chemistry C}, doi = {10.1021/acs.jpcc.2C01142}, pages = {9076 -- 9090}, year = {2022}, language = {en} } @article{BredolKynastDInga2021, author = {Bredol, Michael and Kynast, Ulrich and DInga, Daniel K.}, title = {Novel Approach toward Water-Soluble Singlet Oxygen Monitors Based on Hybrid Inorganic-Organic Nanoclay}, series = {The Journal of Physical Chemistry C}, volume = {125}, journal = {The Journal of Physical Chemistry C}, issn = {1932-7447}, doi = {10.1021/acs.jpcc.1c04785}, pages = {21496 -- 21502}, year = {2021}, language = {en} } @article{BredolVoigtGonabadi2021, author = {Bredol, Michael and Voigt, Dominik and Gonabadi, Atoosa}, title = {A general strategy for CuInS2 based quantum dots with adjustable surface chemistry}, series = {Optical Materials}, volume = {115}, journal = {Optical Materials}, doi = {10.25974/fhms-13734}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:836-opus-137346}, pages = {110994 -- 111005}, year = {2021}, abstract = {Different from negatively charged CuInS2 (CIS) based quantum dots (QDs), positively charged QDs are difficult to obtain in good optical quality, but are desirable for certain applications. We herein present a general synthesis strategy that allows for a universal surface modification of ternary CIS based QDs with thiol containing ligands. The idea behind the synthesis design is, to apply a ZnS shell first for passivating and protecting the core QDs, and then add a second ZnS shell for the functionalization via ligand exchange. Whereby easy ligand exchange with thiolated molecules is systematically set up, by using a weak bonding amine ligand for the second shell. Molecules with various terminal groups were used to functionalize the nanoparticles and stabilize them in different media making any surface charge and polarity accessible. Surface defect chemistry seemed to play an important role in our synthesis strategy, therefore to gain a deeper understanding how these defect sites can alter the electronic structure of core/shell nanoparticles theoretical calculations based on density functional theory were performed, whilst structural, colloidal and optical properties were characterized experimentally (by dynamic light scattering, x-ray diffraction, infrared spectroscopy, zeta potential, absorption- and (time resolved) photoluminescence measurements).}, language = {en} } @article{KasprzyckaAssuncaoBredoletal.2021, author = {Kasprzycka, Ewa and Assun{\c{c}}{\~a}o, Israel and Bredol, Michael and Lezhnina, Marina and Kynast, Ulrich}, title = {Preparation, characterization and optical properties of rare earth complexes with derivatives of N-phenylanthranilic acid}, series = {Journal of Luminescence}, volume = {232}, journal = {Journal of Luminescence}, doi = {10.1016/j.jlumin.2020.117818}, pages = {117818 -- 117825}, year = {2021}, language = {en} } @incollection{Bredol2020, author = {Bredol, Michael}, title = {Electrical and dielectric properties}, series = {Rare Earth Chemistry}, booktitle = {Rare Earth Chemistry}, publisher = {De Gruyter}, address = {Berlin}, isbn = {978-3-11-065360-1}, doi = {10.1515/9783110654929-023}, publisher = {FH M{\"u}nster - University of Applied Sciences}, pages = {349 -- 362}, year = {2020}, language = {en} } @article{IsraelPAssuncaoBredolKasprzyckaetal.2020, author = {Israel P. Assuncao, Israel P. and Bredol, Michael and Kasprzycka, Ewa and Kynast, Ulrich and Lezhnina, Marina}, title = {Near-UV-excitable, green-emitting Tb3+-based complexes}, series = {Inorganica Chimica Acta}, volume = {515}, journal = {Inorganica Chimica Acta}, doi = {10.1016/j.ica.2020.120071}, pages = {120071 -- 120078}, year = {2020}, language = {en} } @article{VoigtSarpongBredol2020, author = {Voigt, Dominik and Sarpong, Larry Kwesi and Bredol, Michael}, title = {Tuning the Optical Band Gap of Semiconductor Nanocomposites - A Case Study with ZnS/Carbon}, series = {Materials}, volume = {13}, journal = {Materials}, doi = {10.3390/ma13184162}, pages = {4162/1 -- 4162/18}, year = {2020}, language = {en} }